This research has produced compounds exhibiting a wide range of structural motifs. It has been demonstrated in compounds 2 to 5 that it is possible to used the Hpap and HCI-pap ligands to create Mn(II)4 and Fe(II)3Fe(III) aggregates with cores similar to the (Fe(III)4O6) single molecular magnets reported by Saalfrank and Gatteschi.
|DATEINAME||An Investigation into the Structure Directing Properties of Organic Templates with Mn, Fe and Cu.pdf|
Structure-Directing Role of Organoamine Ligands in the Self-Assembly of Novel Bimetallic Oxides. Chemistry of Materials 1998, 10 (11) , 3294-3297. DOI: 10.1021/cm980439e. Patricia J. Ollivier and, Thomas E. Mallouk. A “Chimie Douce” Sythesis of Perovskite-Type SrTa2O6 and SrTa2-xNbxO61. Physiological functions of mineral micronutrients …